| 黄剑锋，余蔼英，张美丹，蔡瑛，翁群芳，张耀谋.ß-咔啉-双酰肼类化合物的合成及杀虫活性研究[J].广东农业科学,2013,40(13):91-94 |
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ß-咔啉-双酰肼类化合物的合成及杀虫活性研究 |
| Study on synthesis and biological activity of ß-carboline -3- acylhydrazine |
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| DOI： |
| 中文关键词: ß-咔啉 双酰肼 L-色氨酸 杀虫活性 |
| 英文关键词: ß-carboline diacylhydrazine Tryptophan insecticidal activity |
| 基金项目: |
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| 摘要点击次数: 1401 |
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| 中文摘要: |
| 以L-色氨酸和对三氟甲基苯甲醛为原料，经Pictet-Spengler 环合、酯化、氧化、肼解、酰化5 步反应合成4 个ß-咔啉双酰肼新化合物，通过1H NMR、IR、MS、元素等手段对其结构进行表征，同时测试其最终产物的杀虫活性，结果表明，双酰肼类化合物对库蚊的杀灭效果比较好，特别是化合物A2 和A4，在各个浓度下的杀虫率都达到100%。 |
| 英文摘要: |
| The new compounds of ß-carboline-diacylhydrazine were obtained from L-tryptophan via 5-step reactions, including the Pictet-Spengler condensation, esterification，oxidation，N-alkylation and so on. Their structures were characterized by 1H NMR, IR, MS and elemental analysis. The insecticidal activity tests showed that three compounds of end product exhibited good insecticidal activity. |
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