王维1,2,仓龙1,俞元春2,郝秀珍1.纳米羟基磷灰石对土壤镉化学形态
和水稻镉吸收的影响[J].广东农业科学,2014,41(9):83- |
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纳米羟基磷灰石对土壤镉化学形态
和水稻镉吸收的影响 |
Effect of nano-hydroxyapatite on Cd chemical speciationin soil and Cd accumulation in rice |
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DOI: |
中文关键词: 纳米羟基磷灰石 镉 水稻 形态 土壤 |
英文关键词: nano-hydroxyapatite cadmium rice chemical speciation soil |
基金项目:国家科技支撑计划项目(2011BAD04B04) |
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中文摘要: |
采用吸附等温试验和盆栽试验,研究了nano-HAP 对镉的吸附行为和对土壤镉化学形态及水稻Cd 吸
收的影响。吸附等温试验结果表明,nano-HAP 对镉离子有很高的吸附能力,且其吸附行为可用Langumir 方程和
Freundlich 方程很好地描述;盆栽试验结果表明,nano-HAP 明显提高了土壤溶液中pH 值,显著降低了土壤Cd 的生
物有效性,0.5%、1%和2%施用量的nano-HAP 处理下生物有效态Cd 含量分别下降63.21%、80.62%和92.32%。nano-
HAP 对Cd 污染下的盆载水稻生长也有一定的促进作用,并显著降低了盆栽水稻籽粒中Cd 的含量,且全部达到国家
规定的可食用标准。 |
英文摘要: |
The adsorption behavior of Cd on the surface of Nano-hydroxyapatite (nano-HAP) and the effect of nano-
HAP on the chemical speciation of Cd in soil and the Cd accumulation in rice were studied by the adsorption isotherm
tests and pot experiments. The results showed that nano-HAP had a high adsorption capacity for Cd and the adsorption
behavior could be well described by Langumir and Freundlich equations. The results of pot experiments showed that nano-
HAP significantly increased the pH of soil solution and inhibited Cd bioavailability. The bioavailability of Cd concentration
in the soil decreased by 63.21%, 80.62% and 92.32% under the 0.5%, 1% and 2% nano-HAP treatments, respectively.
Nano-HAP significantly reduced the Cd content in rice grain and all rice grain met the edible standards. |
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